Baker-Venkataraman Rearrangement
Baker-Venkataraman Rearrangement is the base-promoted (KOH) rearrangement of aromatic 2-acyloxy ketones to the corresponding aromatic 1,3-diketone (β-diketones)
Rearrangement Reaction
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Pummerer Rearrangement: Mechanism, Applications Examples
Formation of α-substituted sulfides from the corresponding sulfoxides (must have at least one hydrogen atom at their α-position) is referred to as the Pummerer rearrangement.
Schmidt Reaction (Rearrangement): definition| Mechanism| example
Schmidt reaction is a acid-catalyzed Rearrangement reaction of hydrazoic acid reactions of electrophiles, like carbonyl compounds, alkenes tertiary and alcohols. The following these substrates include amines, nitriles, amides or imines, rearrangement and extrusion of nitrogen.
Favorskii Rearrangement
What is Favorskii Rearrangement explain? Favorskii Rearrangement is organic reaction of α-halo ketones (chlorine, bromine, or iodine) having at least one α-hydrogen, with a nucleophile (alcohol, amine, or H2O) in the presence base (usually an alkoxide or hydroxide) give carboxylic acids or carboxylic acid derivatives via a cyclopropanone intermediate. It is widely used organic reaction … Read more
Baeyer-Villiger Rearrangement (Baeyer-Villiger Oxidation):
The conversion of ketone (cyclic ketone, aromatic ketone, aliphatic ketone) into corresponding esters (lactones) by using MCBPA, or hydrogen peroxide as oxidant and a Lewis acid is known as Baeyer-Villiger oxidation (Baeyer-Villeger Reaction).
Willgerodt-Kindler Reaction
The willgerodt kindler reaction is the modification of the Willgerodt Reaction. It comes under a Rearrangement reaction. The name has been given after Karl Kindler.