Organic Chemistey for JEE|NEET|GATE|NET
Pomeranz-Fritsch Reaction is acid-catalyzed Synthesis of isoquinoline by heatingcyclization of benzalaminoacetals (these are Schiff bases) to give substituted isoquinolines is known as the Pomeranz-Fritsch reaction.
This transformation is referred to as the Prilezhaev reaction for synthesis of oxiranes (epoxides) from isolated double bonds by using peroxycarboxylic acids as oxidizing agents. This method provides products in racemic mixture form.
Schmidt reaction is a acid-catalyzed Rearrangement reaction of hydrazoic acid reactions of electrophiles, like carbonyl compounds, alkenes tertiary and alcohols. The following these substrates include amines, nitriles, amides or imines, rearrangement and extrusion of nitrogen.
The Perkin reaction (or Perkin condensation) is an condensation of aromatic aldehydes and the anhydrides of aliphatic carboxylic acids in the presence of a weak base to obtain α,β-unsaturated carboxylic acids
The conversion of ketone (cyclic ketone, aromatic ketone, aliphatic ketone) into corresponding esters (lactones) by using MCBPA, or hydrogen peroxide as oxidant and a Lewis acid is known as Baeyer-Villiger oxidation (Baeyer-Villeger Reaction).
