Smiles Rearrangement Reaction : Mechanism , Application and Modification

Hello, here is the Smiles Rearrangement Reaction type of nucleophilic aromatic substitution with mechanism, examples, and modification.

Schmidt Reaction (Rearrangement): definition| Mechanism| example

Schmidt Reaction for Synthesis of Nitrile and Amide

Schmidt reaction is a acid-catalyzed Rearrangement reaction of hydrazoic acid reactions of electrophiles, like carbonyl compounds, alkenes tertiary and alcohols. The following these substrates include amines, nitriles, amides or imines, rearrangement and extrusion of nitrogen.

Sandmeyer Reaction: Definition| Mechanism| Example| Application

Sandmeyer reaction : aromatic sn1 mechanism

The Sandmeyer reaction is an organic substitution type reaction used for the synthesis of aryl halide from an aryl diazonium salt. the catalyst used in Sandmeyer reaction is a copper(I) halide like chloride, bromide or iodide ions catalyst. significantly, The reaction include trifluoromethylation, hydroxylation, cyanation, and halogenation type reaction on benzene.