Organic Chemistry Reagents : Here is list of Organic Chemistry Reagents Table containing all oxidizing reagents, reducing reagents, Halogenating reagents, formylation reagents, Trifluoromethyl thiolation Reagents, Cyanating Reagents including there structure application with examples. these reagents are used in Named reaction in organic synthesis.
Table of Page Contents
Oxidizing Reagents (Oxidation):
Metal Oxidants:
- Benzeneseleninic Acid
- Bis(4-methoxyphenyl) Selenoxide
- Bis(tetrabutylammonium) Dichromate
- Chloronitrosyl[N,N ‘-bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediaminato]-ruthenium(IV)
- Lead Tetraacetate (contains Acetic Acid)
- Osmium Catalyst supported on Magnetite (0.07-0.09mmol/g)
- Osmium Tetroxide (4% in Water)
- Phosphomolybdic Acid Hydrate
- Potassium Permanganate
- Pyridinium Chlorochromate
- Pyridinium Dichromate
- Pyridinium Fluorochromate
- Quinolinium Dichromate
- Silver(II) Pyridine-2-carboxylate
- Tetrabutylammonium Perrhenate
- Tetrapropylammonium Perruthenate
Benzeneseleninic Acid:
- Lead Tetraacetate (contains Acetic Acid)
- Osmium Catalyst supported on Magnetite (0.07-0.09mmol/g)
- Osmium Tetroxide (4% in Water)
- Phosphomolybdic Acid Hydrate
- Potassium Permanganate
- Pyridinium Chlorochromate
- Pyridinium Dichromate
- Pyridinium Fluorochromate
- Quinolinium Dichromate
- Silver(II) Pyridine-2-carboxylate
- Tetrabutylammonium Perrhenate
- Tetrapropylammonium Perruthenate
Perchlorates:
- 9-(2-Biphenylyl)-10-methylacridinium Perchlorate
- 9-(2,5-Dimethylphenyl)-10-methylacridinium Perchlorate
- 9-(2,6-Dimethylphenyl)-10-methylacridinium Perchlorate
- 9-Mesityl-10-methylacridinium Perchlorate
- 9-Mesityl-2,7,10-trimethylacridinium Perchlorate
- 10-Methyl-9-phenylacridinium Perchlorate
- Tetrabutylammonium Perchlorate
- Tetraethylammonium Perchlorate
- Tetramethylammonium Perchlorate
Organic Peroxides :
- Benzoyl Peroxide (wetted with ca. 25% Water)
- Bis(trimethylsilyl) Peroxide (contains Hexamethyldisiloxane) (ca. 30% in Hexane)
- tert-Butyl Hydroperoxide (70% in Water)
- 3-Chloroperoxybenzoic Acid (contains ca. 30% Water)
- Cumene Hydroperoxide (contains ca. 20% Aromatic Hydrocarbon)
- Di-tert-butyl Peroxide
- Monoperoxyphthalic Acid Magnesium Salt Hexahydrate
Hypervalent Iodine Compounds:
- 1-Acetoxy-5-bromo-1,2-benziodoxol-3(1H)-one (ABBX)
- Barluenga’s Reagent
- [Bis(trifluoroacetoxy)iodo]benzene (PIFA)
- [Bis(trifluoroacetoxy)iodo]pentafl uorobenzene
- 1-(tert-Butylperoxy)-1,2-benziodoxol-3(1H)-one
- Dess-Martin Periodinane (8-12% in Dichloromethane)
- Dess-Martin Periodinane
- Iodobenzene Diacetate (PIDA)
- Iodomesitylene Diacetate
- Iodosobenzene
- 2-Iodosobenzoic Acid
- 2-Iodoxybenzoic Acid (IBX) (stabilized with Benzoic Acid + Isophthalic Acid)
- Koser Reagent
- Poly4-(diacetoxyiodo)styrene
N-Oxides:
- 2,6-Dichloropyridine N-Oxide
- 4-(Dimethylamino)pyridine N-Oxide Hydrate
- 2,6-Lutidine N-Oxide
- 4-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L)
- 4-Methylmorpholine N-Oxide
- Pyridine N-Oxide
- Trimethylamine N-Oxide Anhydrous
- Trimethylamine N-Oxide Dihydrate
Others Oxidizing Reagents:
Organic Bismuth Compounds
- Triphenylbismuth Dichloride
- Triphenyl-2,6-xylylbismuthonium Tetrafl uoroborate
- Tris(2-methoxyphenyl)bismuth Dichloride
- Tris(4-trifl uoromethylphenyl)bismuth Dichloride
- Tri-o-tolylbismuth Dichloride
Others Oxidants:
- 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafl uoroborate
- Ammonium Cerium(IV) Nitrate
- Bis(tetrabutylammonium) Peroxydisulfate
- Bromanil
- N-Bromosuccinimide
- N-tert-Butylbenzenesulfenamide
- N-tert-Butylbenzenesulfi nimidoyl Chloride
- tert-Butyl Hypochlorite
- (2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
- (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
- Chloramine T Trihydrate
- Chloranil
- o-Chloranil
- Dichloramine T
- 2-Hydroxy-2-azaadamantane
- N-Iodosuccinimide
- 1-Methyl-3-[6-(methylsulfi nyl)hexyl]imidazolium p-Toluenesulfonate
- 1-Methyl-3-[6-(methylthio)hexyl]imidazolium p-Toluenesulfonate
- Potassium Peroxymonosulfate [>45%(T) as KHSO5]
- Pyridine – Sulfur Trioxide Complex
- Tetrapropylammonium Perruthenate
Reducing Reagents (Reduction) :
for reduction the Organic Chemistry Reagents Table is as follow
Metal Hydrides Reagents:
Aluminum Hydrides Reagents
- Diisobutylaluminum Hydride (17% in Toluene, ca. 1.0mol/L)
- Diisobutylaluminum Hydride (19% in Hexane, ca. 1.0mol/L)
- Lithium Aluminum Hydride (Powder)
- Lithium Aluminum Hydride (10% in Tetrahydrofuran, ca. 2.5mol/L)
- Lithium Tri-tert-butoxyaluminum Hydride (ca. 30% in Tetrahydrofuran, ca. 1.0mol/L)
- Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L)
Tin Hydrides Reagents
- Tributyltin Hydride (stabilized with BHT)
Other Metal Hydrides Reagents:
- Sodium Hydride (60%, dispersion in Paraffin Liquid)
- Zirconocene Chloride Hydride
Borohydrides Reagents:
- Bis(triphenylphosphine)copper Tetrahydroborate
- Lithium Borohydride (ca. 3mol/L in Tetrahydrofuran)
- Lithium Tri-sec-butylborohydride (ca. 21% in Tetrahydrofuran, ca. 1.0mol/L)
- (Polystyrylmethyl)trimethylammonium Cyanoborohydride cross-linked with
- Potassium Borohydride
- Potassium Tri-sec-butylborohydride
- Sodium Borohydride
- Sodium Cyanoborohydride
- Sodium Triacetoxyborohydride
- Sodium Tris(1,1,1,3,3,3-hexafluoroisopropoxy)borohydride
- Tetrabutylammonium Borohydride
- Tetramethylammonium Borohydride
- Tetramethylammonium Triacetoxyborohydride
Boranes Reagents:
- 1,2-Bis(tert-butylthio)ethane Borane
- Borane – Tetrahydrofuran Complex
- (stabilized with Sodium Borohydride)
- N,N-Diethylaniline Borane
- Dimethyl Sulfide Borane
Other Boranes Reagents:
- (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)
- (-)-B-Chlorodiisopinocampheylborane (55-65% in Heptane, ca. 1.7mol/L)
- (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)
- (+)-Isopinocampheylborane TMEDA Complex
- (-)-Isopinocampheylborane TMEDA Complex
Silanes Reagents:
- Chlorodiisopropylsilane
- Chlorodimethylsilane
- Diethoxymethylsilane [Hydrosilylating Reagent]
- Dimethylphenylsilane
- Diphenylsilane
- Diphenylsilane
- Methyldiphenylsilane
- Phenylsilane
- 1,1,3,3-Tetramethyldisiloxane
- 1,1,2,2-Tetraphenyldisilane
- Trichlorosilane
- Triethylsilane
- Triisopropylsilane
- Triphenylsilane
- Tris(trimethylsilyl)silane (stabilized with TBBP)
Hydrazines, Hydrazides:
- 3-Chlorobenzohydrazide
- Hydrazine Anhydrous
- Hydrazine Monohydrate
- Hydrazine Dihydrobromide Hydrate
- Hydrazine Dihydrochloride
- Hydrazine Monohydrobromide
- Hydrazine Monohydrochloride
- N ‘-Isopropylidene-2-nitrobenzenesulfonohydrazide
Others Reagents
- Di-tert-butyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Hydriodic Acid
- Samarium(II) Iodide
- Triethyl Phosphite
- Trimethyl Phosphite
- Triphenylphosphine
- Triphenylphosphine Selenide
Halogenation
Fluorination Reagents:
these are the Fluorinating reagents used for Fluorination reaction
- Bis(2-methoxyethyl)aminosulfur Trifluoride
- 4-tert-Butyl-2,6-dimethylphenylsulfur Trifl uoride (FLUOLEADTM)
- (Diethylamino)sulfur Trifluoride (DAST)
- 1,1′-Difl uoro-2,2′-bipyridinium Bis(tetrafl uoroborate)
- N-Fluorobenzenesulfonimide (NFSI)
- N-Fluoro-N ‘-(chloromethyl)triethylenediamine Bis(tetrafluoroborate) (F-TEDA-BF4)
- 1-Fluoro-2,6-dichloropyridinium Tetrafluoroborate
- 2-Fluoro-1-methylpyridinium p-Toluenesulfonate
- 1-Fluoropyridinium Tetrafluoroborate
- 1-Fluoropyridinium Trifluoromethanesulfonate
- 1-Fluoro-2,4,6-trimethylpyridinium Tetrafluoroborate
- 1-Fluoro-2,4,6-trimethylpyridinium Trifluoromethanesulfonate
- Ishikawa’s Reagent
- Morpholinosulfur Trifluoride (Morph-DAST)
- Potassium Fluoride
- Potassium Hydrogenfluoride
- Pyridinium Poly(hydrogenfluoride)
- Tetrabutylammonium Bifluoride
- Tetrabutylammonium Difluorotriphenylsilicate
- Tetrabutylammonium Difluorotriphenylstannate
- Tetrabutylammonium Dihydrogen Trifluoride
- Tetrabutylammonium Fluoride Hydrate
- Tetrabutylammonium Fluoride
- Tetraethylammonium Fluoride Tetrahydrofluoride
- Tetraethylammonium Fluoride Trihydrofluoride
- Tetramethylammonium Fluoride Tetrahydrate
- Triethylamine Pentahydrofluoride
- Triethylamine Trihydrofluoride
Chlorination Reagents:
these are the Chlorination reagents used for Chlorination reaction
- Benzyltrimethylammonium Tetrachloroiodate
- tert-Butyl Hypochlorite
- Chloramine B Hydrate
- Chloramine T Trihydrate
- o-Chloramine T
- Chloromethyl Methyl Ether
- N-Chlorophthalimide
- N-Chlorosuccinimide
- Cyanuric Chloride
- Dichloramine
- Dichloromethyl Methyl Ether
- Methanesulfonyl Chloride
- Methoxyacetyl Chloride
- Oxalyl Chloride
- Sodium Dichloroisocyanurate
- Thionyl Chloride (ca. 1mol/L in Dichloromethane)
- Thionyl Chloride
- Trichloroisocyanuric
- Trichloromethanesulfonyl Chloride
Bromination Reagents:
these are the Bromination reagents used for Bromination reaction
- Benzyltrimethylammonium Tribromide
- Bis(2,4,6-trimethylpyridine)bromonium Hexafl uorophosphate
- Boron Tribromide (17% in Dichloromethane, ca. 1mol/L)
- Bromine
- N-Bromoacetamide
- 2-Bromo-2-cyano-N,N-dimethylacetamide
- Bromodimethylsulfonium Bromide
- N-Bromophthalimide
- N-Bromosaccharin
- N-Bromosuccinimide
- Bromotrichloromethane
- 1-Butyl-3-methylimidazolium Tribromide
- 1,8-Diazabicyclo[5.4.0]-7-undecene Hydrogen Tribromide
- 1,3-Dibromo-5,5-dimethylhydantoin
- Dibromoisocyanuric Acid
- 5,5-Dibromomeldrum’s Acid (=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane)
- 1,2-Dibromo-1,1,2,2-tetrachloroethane
- 4-Dimethylaminopyridinium Bromide Perbromide
- Monosodium Bromoisocyanurate Hydrate
- Phosphorus Tribromide
- Pyridinium Bromide Perbromide
- 2,4,4,6-Tetrabromo-2,5-cyclohexadienone
- Tetrabutylammonium Tribromide
- Trimethylphenylammonium Tribromide
Iodination Reagents:
these are the Iodination reagents used for Iodination reaction
- Benzyltrimethylammonium Dichloroiodate
- Bis(pyridine)iodonium Tetrafl uoroborate
- Bis(2,4,6-trimethylpyridine)iodonium Hexafluorophosphate
- 1-Chloro-2-iodoethane (stabilized with Copper chip)
- 1,3-Diiodo-5,5-dimethylhydantoin
- N,N-Dimethyl-N-(methylsulfanylmethylene)ammonium Iodide
- Hydriodic Acid (57%)
- Iodine
- N-Iodosaccharin
- N-Iodosuccinimide
- Pyridine Iodine Monochloride
- Tetramethylammonium Dichloroiodate
- Trimethylsilyl Iodide (stabilized with Aluminum)
Trifluoromethylation Reagents:
these are the Trifluoromethylation reagents used for Trifluoromethylation reaction
- Methyl Difluoro(fluorosulfonyl)acetate
- [(Oxido)phenyl(trifl uoromethyl)-λ4-sulfanylidene]dimethylammonium Tetrafluoroborate
- (1,10-Phenanthroline)(trifluoromethyl)(triphenylphosphine)copper(I)
- Sodium Trifluoroacetate
- Sodium Trifluoromethanesulfinate
- Triethyl(trifluoromethyl)silane
- 1-Trifluoromethyl-1,2-benziodoxol-3(1H)-one (contains 60% Diatomaceous earth)
- 1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole
- (Trifluoromethyl)trimethylsilane
- (Trifluoromethyl)tris(triphenylphosphine)copper(I)
- Zinc(II) Bis(trifluoromethanesulfinate) Dihydrate
Trifluoromethylthiolation Reagents:
these are the Trifluoromethylthiolation reagents used for Trifluoromethylthiolation reaction
- Benzoyl(phenyliodonio)(trifl uoromethanesulfonyl)methanide
- Copper(I) Trifl uoromethanethiolate
- N-Methyl-N-(trifl uoromethylthio)aniline
- N-(Trifl uoromethylthio)phthalimide
Formylation Reagents:
These are the Formylation reagents used for formylation reaction
- 1H-Benzotriazole-1-carboxaldehyde
- (Chloromethylene)dimethyliminium Chloride
- F-Cyanomethyl Formate
- Dichloromethyl Methyl Ether
- N-(Diethylcarbamoyl)-N-methoxyformamide
- Diethyl Phenyl Orthoformate
- N,N-Dimethylformamide
- 1-(2,4-Dinitrophenyl)pyridinium Chloride
- Ethyl Formate
- Ethyl N-Phenylformimidate
- Formic Acid
- 4-Formylmorpholine
- 1-Formylpiperidine
- N-Formylsaccharin
- Gold’s Reagent
- Hexamethylenetetramine
- N-Methylformanilide
- N-Methyl-N-(2-pyridyl)formamide
- Paraformaldehyde
- Triethyl Orthoformate
- 2,2,2-Trifluoroethyl Formate
- Trimethyl Orthoformate
- Tris(1H-benzotriazol-1-yl)methane
Cyanating Reagents (Cyanation):
These are the Cyanating reagents used for Cyanation reaction
- Acetone Cyanohydrin
- Benzyl Thiocyanate
- tert-Butyl Isocyanide
- 2-Chlorobenzyl Thiocyanate
- Copper(I) Cyanide
- Diethyl Cyanophosphonate
- Ethyl Cyanoacetate
- Potassium Cyanide
- p-Toluenesulfonylmethyl Isocyanide
- Trimethylsilyl Cyanide
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My name is Pradip Sanjay W. I’m an organic chemist originally from Maharashtra, India. I have qualified UGC NET-JRF, GATE in chemical sciences and MH-SET exam for assistant professor. I’m currently pursuing my Ph.D. in organic chemistry at the Indian Institute of Technology Hyderabad, India.
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