Carroll Rearrangement: Mechanism | Examples

The Carroll Rearrangement is a named reaction in organic chemistry, where the [3,3]-sigmatropic rearrangement of allylic β-keto esters to form γ,δ-unsaturated ketones is called the Carroll rearrangement. It is also known as the Kimel–Cope or decarboxylative Claisen rearrangement. Here, we will explore the Carroll rearrangement and its mechanism, accompanied by some interesting examples. Carroll Rearrangement … Read more

Cannizzaro Reaction: Mechanism | Examples

Cannizzaro Reaction is a base-catalyzed redox reaction in which aromatic aldehydes, formaldehyde, or other aliphatic aldehydes lacking α-hydrogen are converted into the corresponding alcohols and carboxylic acids. Cannizzaro reaction is a named reaction in organic chemistry. Here, we will explore the Cannizzaro Reaction and its mechanism, accompanied by some interesting examples. Cannizzaro Reaction Mechanism: Several … Read more

Aldol Reaction: Condition | Mechanism | Examples

Definitionn: The Aldol reaction is a versatile carbon-carbon bond-forming reaction in organic chemistry. It involves the condensation of an enol or enolate (derived from a carbonyl compound) with another carbonyl compound, forming a β-hydroxy carbonyl compound, known as an aldol product. The reaction takes its name from the combination of “aldehyde” and “alcohol,” as the … Read more

Alder Ene Reaction

The Alder Ene reaction, also known as the Alder-ene reaction or the ene reaction, is a type of pericyclic reaction in organic chemistry. It involves the addition of a π-bond (ene) to an unsaturated double bond (eneophile) in the presence of a Lewis acid or a transition metal catalyst. The reaction proceeds through a concerted … Read more