Organic Chemistey for JEE|NEET|GATE|NET
Sommelet-Hauser rearrangement is one of the thermal [2,3]-sigmatropic rearrangements, in which the benzylic quaternary ammonium salts are treated within the presence of a strong base like NaNH2, KNH2, as well as alkyl lithium to prepare the Substituted 3° benzylic amine.
The Carroll Rearrangement is a named reaction in organic chemistry, where the [3,3]-sigmatropic rearrangement of allylic β-keto esters to form γ,δ-unsaturated ketones is called the Carroll rearrangement. It is also known as the Kimel–Cope or decarboxylative Claisen rearrangement. Here, we will explore the Carroll rearrangement and its mechanism, accompanied by some interesting examples. Carroll Rearrangement … Read more
Cannizzaro Reaction is a base-catalyzed redox reaction in which aromatic aldehydes, formaldehyde, or other aliphatic aldehydes lacking α-hydrogen are converted into the corresponding alcohols and carboxylic acids. Cannizzaro reaction is a named reaction in organic chemistry. Here, we will explore the Cannizzaro Reaction and its mechanism, accompanied by some interesting examples. Cannizzaro Reaction Mechanism: Several … Read more
The addition of aliphatic or aromatic aldehydes across activated double bonds in the presence of a nucleophilic catalyst for the synthesis of 1,4-diketones and γ-oxo nitriles is known as the Stetter reaction.
Suzuki cross -coupling reaction is an coupling reaction and also known as Suzuki-Miyaura cross-coupling, its coupling between a boronic acid and an organohalide or aromatic halides by using Palladium (0) complex is used to catalyst and base.
Arbuzov reaction also known as Michaelis–Arbuzov reaction and its important Name Reaction In Organic Chemistry. Here is the all about Arbuzov Reaction with Mechanism and Examples, Application.