Organic Chemistey for JEE|NEET|GATE|NET
Schmidt reaction is a acid-catalyzed Rearrangement reaction of hydrazoic acid reactions of electrophiles, like carbonyl compounds, alkenes tertiary and alcohols. The following these substrates include amines, nitriles, amides or imines, rearrangement and extrusion of nitrogen.
The Perkin reaction (or Perkin condensation) is an condensation of aromatic aldehydes and the anhydrides of aliphatic carboxylic acids in the presence of a weak base to obtain α,β-unsaturated carboxylic acids
The conversion of ketone (cyclic ketone, aromatic ketone, aliphatic ketone) into corresponding esters (lactones) by using MCBPA, or hydrogen peroxide as oxidant and a Lewis acid is known as Baeyer-Villiger oxidation (Baeyer-Villeger Reaction).
Takai reaction is a general carbon-carbon bond-forming reaction in organic chemistry. Takai reaction is also known as takai -Utimoto olefination, This transformation is referred to as the name of Kazuhiko Takai. This olefination is a simple alternative for the Wittig reaction and other complex methods like preparing an E alkene stereoselective (major) isomer. In this method, chromium(II) catalyst was used to prepare (E) configuration of alkenyl halides from corresponding carbonyl compounds like aldehyde and ketones.
Swern oxidation for amino acid synthesis organic chemistry
