Organic Chemistry Reagents Table

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Organic Chemistry Reagents : Here is list of Organic Chemistry Reagents Table containing all oxidizing reagents, reducing reagents, Halogenating reagents, formylation reagents, Trifluoromethyl thiolation Reagents, Cyanating Reagents including there structure application with examples. these reagents are used in Named reaction in organic synthesis.

Oxidizing Reagents (Oxidation):

Metal Oxidants:

Oxidizing Reagents (Oxidation) Metal Oxidants
Metal Oxidants
  1. Benzeneseleninic Acid
  2. Bis(4-methoxyphenyl) Selenoxide
  3. Bis(tetrabutylammonium) Dichromate
  4. Chloronitrosyl[N,N ‘-bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediaminato]-ruthenium(IV)
  5. Lead Tetraacetate (contains Acetic Acid)
  6. Osmium Catalyst supported on Magnetite (0.07-0.09mmol/g)
  7. Osmium Tetroxide (4% in Water)
  8. Phosphomolybdic Acid Hydrate
  9. Potassium Permanganate
  10. Pyridinium Chlorochromate
  11. Pyridinium Dichromate
  12. Pyridinium Fluorochromate
  13. Quinolinium Dichromate
  14. Silver(II) Pyridine-2-carboxylate
  15. Tetrabutylammonium Perrhenate
  16. Tetrapropylammonium Perruthenate

Benzeneseleninic Acid:

  1. Lead Tetraacetate (contains Acetic Acid)
  2. Osmium Catalyst supported on Magnetite (0.07-0.09mmol/g)
  3. Osmium Tetroxide (4% in Water)
  4. Phosphomolybdic Acid Hydrate
  5. Potassium Permanganate
  6. Pyridinium Chlorochromate
  7. Pyridinium Dichromate
  8. Pyridinium Fluorochromate
  9. Quinolinium Dichromate
  10. Silver(II) Pyridine-2-carboxylate
  11. Tetrabutylammonium Perrhenate
  12. Tetrapropylammonium Perruthenate

Perchlorates:

Perchlorates
Perchlorates containing oxidants
  1. 9-(2-Biphenylyl)-10-methylacridinium Perchlorate
  2. 9-(2,5-Dimethylphenyl)-10-methylacridinium Perchlorate
  3. 9-(2,6-Dimethylphenyl)-10-methylacridinium Perchlorate
  4. 9-Mesityl-10-methylacridinium Perchlorate
  5. 9-Mesityl-2,7,10-trimethylacridinium Perchlorate
  6. 10-Methyl-9-phenylacridinium Perchlorate
  7. Tetrabutylammonium Perchlorate
  8. Tetraethylammonium Perchlorate
  9. Tetramethylammonium Perchlorate

Organic Peroxides :

Organic Peroxides
Organic Peroxides Reagents for oxidation
  1. Benzoyl Peroxide (wetted with ca. 25% Water)
  2. Bis(trimethylsilyl) Peroxide (contains Hexamethyldisiloxane) (ca. 30% in Hexane)
  3. tert-Butyl Hydroperoxide (70% in Water)
  4. 3-Chloroperoxybenzoic Acid (contains ca. 30% Water)
  5. Cumene Hydroperoxide (contains ca. 20% Aromatic Hydrocarbon)
  6. Di-tert-butyl Peroxide
  7. Monoperoxyphthalic Acid Magnesium Salt Hexahydrate

Hypervalent Iodine Compounds:

Hypervalent Iodine Compounds
Hypervalent Iodine containing oxidizing reagents
  1. 1-Acetoxy-5-bromo-1,2-benziodoxol-3(1H)-one (ABBX)
  2. Barluenga’s Reagent
  3. [Bis(trifluoroacetoxy)iodo]benzene (PIFA)
  4. [Bis(trifluoroacetoxy)iodo]pentafl uorobenzene
  5. 1-(tert-Butylperoxy)-1,2-benziodoxol-3(1H)-one
  6. Dess-Martin Periodinane (8-12% in Dichloromethane)
  7. Dess-Martin Periodinane
  8. Iodobenzene Diacetate (PIDA)
  9. Iodomesitylene Diacetate
  10. Iodosobenzene
  11. 2-Iodosobenzoic Acid
  12. 2-Iodoxybenzoic Acid (IBX) (stabilized with Benzoic Acid + Isophthalic Acid)
  13. Koser Reagent
  14. Poly4-(diacetoxyiodo)styrene

N-Oxides:

N-Oxides
N- Oxide Containing oxidizing Reagents
  1. 2,6-Dichloropyridine N-Oxide
  2. 4-(Dimethylamino)pyridine N-Oxide Hydrate
  3. 2,6-Lutidine N-Oxide
  4. 4-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L)
  5. 4-Methylmorpholine N-Oxide
  6. Pyridine N-Oxide
  7. Trimethylamine N-Oxide Anhydrous
  8. Trimethylamine N-Oxide Dihydrate

Others Oxidizing Reagents:

Organic Bismuth Compounds

  1. Triphenylbismuth Dichloride
  2. Triphenyl-2,6-xylylbismuthonium Tetrafl uoroborate
  3. Tris(2-methoxyphenyl)bismuth Dichloride
  4. Tris(4-trifl uoromethylphenyl)bismuth Dichloride
  5. Tri-o-tolylbismuth Dichloride

Others Oxidants:

Oxidants
Others Oxidizing reagents
  1. 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafl uoroborate
  2. Ammonium Cerium(IV) Nitrate
  3. Bis(tetrabutylammonium) Peroxydisulfate
  4. Bromanil
  5. N-Bromosuccinimide
  6. N-tert-Butylbenzenesulfenamide
  7. N-tert-Butylbenzenesulfi nimidoyl Chloride
  8. tert-Butyl Hypochlorite
  9. (2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
  10. (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
  11. Chloramine T Trihydrate
  12. Chloranil
  13. o-Chloranil
  14. Dichloramine T
  15. 2-Hydroxy-2-azaadamantane
  16. N-Iodosuccinimide
  17. 1-Methyl-3-[6-(methylsulfi nyl)hexyl]imidazolium p-Toluenesulfonate
  18. 1-Methyl-3-[6-(methylthio)hexyl]imidazolium p-Toluenesulfonate
  19. Potassium Peroxymonosulfate [>45%(T) as KHSO5]
  20. Pyridine – Sulfur Trioxide Complex
  21. Tetrapropylammonium Perruthenate

Reducing Reagents (Reduction) :

for reduction the Organic Chemistry Reagents Table is as follow

Metal Hydrides Reagents:

Aluminum Hydrides Reagents

  1. Diisobutylaluminum Hydride (17% in Toluene, ca. 1.0mol/L)
  2. Diisobutylaluminum Hydride (19% in Hexane, ca. 1.0mol/L)
  3. Lithium Aluminum Hydride (Powder)
  4. Lithium Aluminum Hydride (10% in Tetrahydrofuran, ca. 2.5mol/L)
  5. Lithium Tri-tert-butoxyaluminum Hydride (ca. 30% in Tetrahydrofuran, ca. 1.0mol/L)
  6. Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L)

Tin Hydrides Reagents

  • Tributyltin Hydride (stabilized with BHT)

Other Metal Hydrides Reagents:

  • Sodium Hydride (60%, dispersion in Paraffin Liquid)
  • Zirconocene Chloride Hydride

Borohydrides Reagents:

  1. Bis(triphenylphosphine)copper Tetrahydroborate
  2. Lithium Borohydride (ca. 3mol/L in Tetrahydrofuran)
  3. Lithium Tri-sec-butylborohydride (ca. 21% in Tetrahydrofuran, ca. 1.0mol/L)
  4. (Polystyrylmethyl)trimethylammonium Cyanoborohydride cross-linked with
  5. Potassium Borohydride
  6. Potassium Tri-sec-butylborohydride
  7. Sodium Borohydride
  8. Sodium Cyanoborohydride
  9. Sodium Triacetoxyborohydride
  10. Sodium Tris(1,1,1,3,3,3-hexafluoroisopropoxy)borohydride
  11. Tetrabutylammonium Borohydride
  12. Tetramethylammonium Borohydride
  13. Tetramethylammonium Triacetoxyborohydride

Boranes Reagents:

  1. 1,2-Bis(tert-butylthio)ethane Borane
  2. Borane – Tetrahydrofuran Complex
  3. (stabilized with Sodium Borohydride)
  4. N,N-Diethylaniline Borane
  5. Dimethyl Sulfide Borane

Other Boranes Reagents:

  1. (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)
  2. (-)-B-Chlorodiisopinocampheylborane (55-65% in Heptane, ca. 1.7mol/L)
  3. (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)
  4. (+)-Isopinocampheylborane TMEDA Complex
  5. (-)-Isopinocampheylborane TMEDA Complex

Silanes Reagents:

  1. Chlorodiisopropylsilane
  2. Chlorodimethylsilane
  3. Diethoxymethylsilane [Hydrosilylating Reagent]
  4. Dimethylphenylsilane
  5. Diphenylsilane
  6. Diphenylsilane
  7. Methyldiphenylsilane
  8. Phenylsilane
  9. 1,1,3,3-Tetramethyldisiloxane
  10. 1,1,2,2-Tetraphenyldisilane
  11. Trichlorosilane
  12. Triethylsilane
  13. Triisopropylsilane
  14. Triphenylsilane
  15. Tris(trimethylsilyl)silane (stabilized with TBBP)

Hydrazines, Hydrazides:

  1. 3-Chlorobenzohydrazide
  2. Hydrazine Anhydrous
  3. Hydrazine Monohydrate
  4. Hydrazine Dihydrobromide Hydrate
  5. Hydrazine Dihydrochloride
  6. Hydrazine Monohydrobromide
  7. Hydrazine Monohydrochloride
  8. N ‘-Isopropylidene-2-nitrobenzenesulfonohydrazide

Others Reagents

  1. Di-tert-butyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
  2. Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
  3. Hydriodic Acid
  4. Samarium(II) Iodide
  5. Triethyl Phosphite
  6. Trimethyl Phosphite
  7. Triphenylphosphine
  8. Triphenylphosphine Selenide

Halogenation

Fluorination Reagents:

these are the Fluorinating reagents used for Fluorination reaction

  1. Bis(2-methoxyethyl)aminosulfur Trifluoride
  2. 4-tert-Butyl-2,6-dimethylphenylsulfur Trifl uoride (FLUOLEADTM)
  3. (Diethylamino)sulfur Trifluoride (DAST)
  4. 1,1′-Difl uoro-2,2′-bipyridinium Bis(tetrafl uoroborate)
  5. N-Fluorobenzenesulfonimide (NFSI)
  6. N-Fluoro-N ‘-(chloromethyl)triethylenediamine Bis(tetrafluoroborate) (F-TEDA-BF4)
  7. 1-Fluoro-2,6-dichloropyridinium Tetrafluoroborate
  8. 2-Fluoro-1-methylpyridinium p-Toluenesulfonate
  9. 1-Fluoropyridinium Tetrafluoroborate
  10. 1-Fluoropyridinium Trifluoromethanesulfonate
  11. 1-Fluoro-2,4,6-trimethylpyridinium Tetrafluoroborate
  12. 1-Fluoro-2,4,6-trimethylpyridinium Trifluoromethanesulfonate
  13. Ishikawa’s Reagent
  14. Morpholinosulfur Trifluoride (Morph-DAST)
  15. Potassium Fluoride
  16. Potassium Hydrogenfluoride
  17. Pyridinium Poly(hydrogenfluoride)
  18. Tetrabutylammonium Bifluoride
  19. Tetrabutylammonium Difluorotriphenylsilicate
  20. Tetrabutylammonium Difluorotriphenylstannate
  21. Tetrabutylammonium Dihydrogen Trifluoride
  22. Tetrabutylammonium Fluoride Hydrate
  23. Tetrabutylammonium Fluoride
  24. Tetraethylammonium Fluoride Tetrahydrofluoride
  25. Tetraethylammonium Fluoride Trihydrofluoride
  26. Tetramethylammonium Fluoride Tetrahydrate
  27. Triethylamine Pentahydrofluoride
  28. Triethylamine Trihydrofluoride

Chlorination Reagents:

these are the Chlorination reagents used for Chlorination reaction

  1. Benzyltrimethylammonium Tetrachloroiodate
  2. tert-Butyl Hypochlorite
  3. Chloramine B Hydrate
  4. Chloramine T Trihydrate
  5. o-Chloramine T
  6. Chloromethyl Methyl Ether
  7. N-Chlorophthalimide
  8. N-Chlorosuccinimide
  9. Cyanuric Chloride
  10. Dichloramine
  11. Dichloromethyl Methyl Ether
  12. Methanesulfonyl Chloride
  13. Methoxyacetyl Chloride
  14. Oxalyl Chloride
  15. Sodium Dichloroisocyanurate
  16. Thionyl Chloride (ca. 1mol/L in Dichloromethane)
  17. Thionyl Chloride
  18. Trichloroisocyanuric
  19. Trichloromethanesulfonyl Chloride

Bromination Reagents:

these are the Bromination reagents used for Bromination reaction

  1. Benzyltrimethylammonium Tribromide
  2. Bis(2,4,6-trimethylpyridine)bromonium Hexafl uorophosphate
  3. Boron Tribromide (17% in Dichloromethane, ca. 1mol/L)
  4. Bromine
  5. N-Bromoacetamide
  6. 2-Bromo-2-cyano-N,N-dimethylacetamide
  7. Bromodimethylsulfonium Bromide
  8. N-Bromophthalimide
  9. N-Bromosaccharin
  10. N-Bromosuccinimide
  11. Bromotrichloromethane
  12. 1-Butyl-3-methylimidazolium Tribromide
  13. 1,8-Diazabicyclo[5.4.0]-7-undecene Hydrogen Tribromide
  14. 1,3-Dibromo-5,5-dimethylhydantoin
  15. Dibromoisocyanuric Acid
  16. 5,5-Dibromomeldrum’s Acid (=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane)
  17. 1,2-Dibromo-1,1,2,2-tetrachloroethane
  18. 4-Dimethylaminopyridinium Bromide Perbromide
  19. Monosodium Bromoisocyanurate Hydrate
  20. Phosphorus Tribromide
  21. Pyridinium Bromide Perbromide
  22. 2,4,4,6-Tetrabromo-2,5-cyclohexadienone
  23. Tetrabutylammonium Tribromide
  24. Trimethylphenylammonium Tribromide

Iodination Reagents:

these are the Iodination reagents used for Iodination reaction

  1. Benzyltrimethylammonium Dichloroiodate
  2. Bis(pyridine)iodonium Tetrafl uoroborate
  3. Bis(2,4,6-trimethylpyridine)iodonium Hexafluorophosphate
  4. 1-Chloro-2-iodoethane (stabilized with Copper chip)
  5. 1,3-Diiodo-5,5-dimethylhydantoin
  6. N,N-Dimethyl-N-(methylsulfanylmethylene)ammonium Iodide
  7. Hydriodic Acid (57%)
  8. Iodine
  9. N-Iodosaccharin
  10. N-Iodosuccinimide
  11. Pyridine Iodine Monochloride
  12. Tetramethylammonium Dichloroiodate
  13. Trimethylsilyl Iodide (stabilized with Aluminum)

Trifluoromethylation Reagents:

these are the Trifluoromethylation reagents used for Trifluoromethylation reaction

  1. Methyl Difluoro(fluorosulfonyl)acetate
  2. [(Oxido)phenyl(trifl uoromethyl)-λ4-sulfanylidene]dimethylammonium Tetrafluoroborate
  3. (1,10-Phenanthroline)(trifluoromethyl)(triphenylphosphine)copper(I)
  4. Sodium Trifluoroacetate
  5. Sodium Trifluoromethanesulfinate
  6. Triethyl(trifluoromethyl)silane
  7. 1-Trifluoromethyl-1,2-benziodoxol-3(1H)-one (contains 60% Diatomaceous earth)
  8. 1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole
  9. (Trifluoromethyl)trimethylsilane
  10. (Trifluoromethyl)tris(triphenylphosphine)copper(I)
  11. Zinc(II) Bis(trifluoromethanesulfinate) Dihydrate

Trifluoromethylthiolation Reagents:

these are the Trifluoromethylthiolation reagents used for Trifluoromethylthiolation reaction

  1. Benzoyl(phenyliodonio)(trifl uoromethanesulfonyl)methanide
  2. Copper(I) Trifl uoromethanethiolate
  3. N-Methyl-N-(trifl uoromethylthio)aniline
  4. N-(Trifl uoromethylthio)phthalimide

Formylation Reagents:

These are the Formylation reagents used for formylation reaction

  1. 1H-Benzotriazole-1-carboxaldehyde
  2. (Chloromethylene)dimethyliminium Chloride
  3. F-Cyanomethyl Formate
  4. Dichloromethyl Methyl Ether
  5. N-(Diethylcarbamoyl)-N-methoxyformamide
  6. Diethyl Phenyl Orthoformate
  7. N,N-Dimethylformamide
  8. 1-(2,4-Dinitrophenyl)pyridinium Chloride
  9. Ethyl Formate
  10. Ethyl N-Phenylformimidate
  11. Formic Acid
  12. 4-Formylmorpholine
  13. 1-Formylpiperidine
  14. N-Formylsaccharin
  15. Gold’s Reagent
  16. Hexamethylenetetramine
  17. N-Methylformanilide
  18. N-Methyl-N-(2-pyridyl)formamide
  19. Paraformaldehyde
  20. Triethyl Orthoformate
  21. 2,2,2-Trifluoroethyl Formate
  22. Trimethyl Orthoformate
  23. Tris(1H-benzotriazol-1-yl)methane

Cyanating Reagents (Cyanation):

These are the Cyanating reagents used for Cyanation reaction

  1. Acetone Cyanohydrin
  2. Benzyl Thiocyanate
  3. tert-Butyl Isocyanide
  4. 2-Chlorobenzyl Thiocyanate
  5. Copper(I) Cyanide
  6. Diethyl Cyanophosphonate
  7. Ethyl Cyanoacetate
  8. Potassium Cyanide
  9. p-Toluenesulfonylmethyl Isocyanide
  10. Trimethylsilyl Cyanide

Related Topic – All Name Reaction Of Organic Chemistry with Mechanism and Examples.

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