Aza-Cope Rearrangement : Mechanism| Examples | Application
Aza-Cope Rearrangement Mechanism, Examples and Applications
Organic Chemistey for JEE|NEET|GATE|NET
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Aza-Cope Rearrangement Mechanism, Examples and Applications
Baker-Venkataraman Rearrangement is the base-promoted (KOH) rearrangement of aromatic 2-acyloxy ketones to the corresponding aromatic 1,3-diketone (β-diketones)
Formation of α-substituted sulfides from the corresponding sulfoxides (must have at least one hydrogen atom at their α-position) is referred to as the Pummerer rearrangement.
The rearrangements reactions are important Name reaction in organic chemistry. Wittig rearrangement, first reported by G. Wittig and L. Löhmann in 1942, The Wittig rearrangement converts α-metalated ethers to metal alkoxides, yielding secondary or tertiary alcohols. Its nitrogen analog, the aza-Wittig rearrangement, transforms α-metalated tertiary amines into rearranged metal amides, producing homoallylic secondary amines. This … Read more